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style="font-size:16px;font-family:"Microsoft YaHei";">因煤化工行業廢水處理裝置普遍存在臭味重，嚴重影響廠區空氣質量及職工的工作環境，未能滿足環保要求，針對此問題煤化工企業應采取哪種除臭技術，并對現有除臭技術的工藝原理進行分析。</span><br /> <span style="font-size:16px;font-family:"Microsoft YaHei";"> 節能減排從廣義上是指節約物質資源和能量資源，減少廢棄物和環境有害物 (包括廢水、廢氣、廢渣和噪聲) 排放，石化企業在為社會提供能量資源的同時，在不斷向環境中排放廢棄物和有害物。隨著經濟的發展和人們生活水平的提高，人們對工作和生活環境的要求也逐漸提高，惡臭作為七大環境公害之一已越來越受到人們的關注。而煤化工企業的廢水惡臭是一種成分極其復雜的高濃度氣體，加之污水處理廠惡臭濃度變化大的特殊性，治理效果不甚理想，而近年來以生物降解惡臭氣體的治理技術日趨成熟、完善。</span><br /> <span style="font-size:16px;font-family:"Microsoft YaHei";">1 煤化工企業廢水惡臭成分、來源及危害</span><br /> <span style="font-size:16px;font-family:"Microsoft YaHei";">1.1 煤化工企業廢水惡臭成分</span><br /> <span style="font-size:16px;font-family:"Microsoft YaHei";"> 惡臭物質的種類繁多，目前能為人們所感知的有 4000 多種，其中被公認的主要惡臭物質從其組成可分為五大類①含硫的化合物，如H2S、硫醇類、硫醚類；②含氮的化合物，如胺類、酰胺、吲哚類；③鹵素及衍生物，如氯氣、鹵代烴；④烴類，如烷烴、烯烴、炔烴、芳香烴； ⑤ 含氧的有機物，如醇、酚、醛、酮、有機酸等。煤化工行業排放的惡臭污染物主要有八大物質： ①硫化氫；②氨； ③甲硫醇； ④甲硫醚；⑤三甲胺；⑥二甲二硫； ⑦二硫化碳；⑧苯乙烯。其它還有甲烷、糞臭素、吲哚等微量有機組分氣體。由于成分相當復雜且都具揮發性物質，所以其感官體現為綜合性惡臭異味。這些物質都帶有活性基團，容易發生化學反應，易被氧化。當活性基團被氧化后，氣味就消失，各種除臭工藝就是基于這一原理。</span><br /> <span style="font-size:16px;font-family:"Microsoft YaHei";">1.2 污水處理廠惡臭的主要來源</span><br /> <span style="font-size:16px;font-family:"Microsoft YaHei";"> 根據相關設計單位在煤化工行業的實際現場測定，煤化工企業污水處理場惡臭污染物散發源主要有總進口、隔油池、浮選池、生物曝氣池、污油(泥)池、污泥脫水間等?？傔M口、隔油池、浮選池散發的惡臭污染物以揮發性有機物(VOC)為主，濃度在幾千到幾萬mg/m3，還有一定量的硫化物和氨等。生物曝氣池、污油(泥)池、污泥脫水間散發的污染物有硫化氫、硫醇、硫醚、氨、烴類化合物，濃度在幾個到幾百 mg/ m3。</span><br /> <span style="font-size:16px;font-family:"Microsoft YaHei";">1.3 污水處理廠惡臭的危害</span><br /> <span style="font-size:16px;font-family:"Microsoft YaHei";"> 污水處理過程中產生的惡臭對環境污染主要表現在兩個方面：</span><br /> <span style="font-size:16px;font-family:"Microsoft YaHei";"> (1) 刺激嗅覺器官引起人們不愉快或厭惡，損害人體健康，對人體呼吸、消化、心血管、內分泌及神經系統都會造成不同程度的毒害，其中芳香族化合物如苯、甲苯、苯乙烯等還能使人體產生畸變、癌變。</span><br /> <span style="font-size:16px;font-family:"Microsoft YaHei";"> (2)對金屬材料、設備和管道有一定的腐蝕性。</span><br /> <span style="font-size:16px;font-family:"Microsoft YaHei";">2 現階段各種除臭技術比較</span><br /> <span style="font-size:16px;font-family:"Microsoft YaHei";"> 目前國內常規廢水除臭技術包括生物除臭法、化學吸收法、活性炭吸附法等除臭工藝，除臭工藝的優劣比較：</span><br /> <br /> <span style="font-size:16px;font-family:"Microsoft YaHei";">(1)生物過濾法</span><br /> <span style="font-size:16px;font-family:"Microsoft YaHei";"> 優點：第一，簡單經濟高效吸收率達到90%以上；第二，低投資，操作和維護費用低，運行、維護量??；第三，不產生二次污染。</span><br /> <span style="font-size:16px;font-family:"Microsoft YaHei";"> 缺點：第一，占地面積稍大；第二，對溫度、pH、濕度要求較高；第三，表面負荷過大會產生阻塞；第四，對混合臭氣需要不同的菌種，需要提供有效菌種。</span><br /> <br /> <span style="font-size:16px;font-family:"Microsoft YaHei";">(2)化學吸收法</span><br /> <span style="font-size:16px;font-family:"Microsoft YaHei";"> 優點：較高的去除率和可靠的處理方法，可高達95%以上；第二，可處理氣量大、濃度高的惡臭污染物；第三，多級的洗滌，可去除各種混合的惡臭污染物；第四，占地面積小，土建投資??；第五，運行穩定，停機后可迅速恢復到穩定的工作狀態。</span><br /> <span style="font-size:16px;font-family:"Microsoft YaHei";">缺點：維修要求高；第二，運行管理較復雜，對操作人員素質要求較高；第三，運行費用稍高，包括能耗、藥耗等部分。</span><br /> <span style="font-size:16px;font-family:"Microsoft YaHei";">(3)<a href="/" target="_blank">活性炭吸附</a>法</span><br /> <span style="font-size:16px;font-family:"Microsoft YaHei";"> 優點：第一，可有效去除VOC；第二，對低濃度的惡臭物質的去除經濟有效可靠；第三，維護簡單，可用于濕式化學吸收后的深度處理。</span><br /> <span style="font-size:16px;font-family:"Microsoft YaHei";"> 缺點：第一，對于硫化氫等去除率有限；第二，不能用于大氣量和高濃度情況；第三，活性炭的再生和替換價格昂貴、勞動價格大；第四，再生后的活性炭吸附能力降低。</span><br /> <span style="font-size:16px;font-family:"Microsoft YaHei";">(4)臭氧氧化法</span><br /> <span style="font-size:16px;font-family:"Microsoft YaHei";"> 優點：簡單易行，占地面積小，維護量小。</span><br /> <p> <span style="font-size:16px;font-family:"Microsoft YaHei";"> 缺點：第一，臭氧本身為污染物，經過處理后仍有輕微惡臭味；第二，使用工況變化能力差，因而工藝控制復雜困難；第三，功率要求高；第四，對殘余臭氧的分解處理的費用昂貴。第五，殘余的臭氧會腐蝕金屬構件、后續處理費用大。</span> </p> <p> <span style="font-size:16px;font-family:"Microsoft YaHei";"><img src="http://img01.fuhai360.com/--50/50117/202304/202304191429510191.jpg" alt="" /><br /> </span> </p><div style="padding:20px 10px;text-align:right;">（此內容由<a 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